ChemInform Abstract: Synthesis of β-Substituted Cyclic Enones via Phosphonium Salt-Activated, Palladium-Catalyzed Cross-Coupling of Cyclic 1,3-Diones.

Shyh-Ming Yang,Gee-Hong Kuo,Michael D. Gaul,William V. Murray

ChemInform（2016）

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摘要

Activation of cyclic 1,3‐diones with PyBroP generates phosphonium salt intermediates which readily undergo Pd‐catalyzed Suzuki—Miyaura coupling with boronic acids and pinacol esters as well as Pd/Cu‐catalyzed Sonogashira coupling with terminal alkynes.

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cheminform abstract,synthesis,salt-activated,palladium-catalyzed,cross-coupling

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