ChemInform Abstract: Tunable P-Chiral Bisdihydrobenzooxaphosphole Ligands for Enantioselective Hydroformylation.

Renchang Tan,Xin Zheng,Bo Qu,C. Avery Sader,Keith R. Fandrick,Chris H. Senanayake,Xumu Zhang

ChemInform（2016）

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摘要

Air-stable and tunable chiral bisdihydrobenzooxaphosphole ligands (BIBOPs) were employed in rhodium-catalyzed asymmetric hydroformylation of various terminal olefins with excellent conversions (>99%), moderate-to-excellent enantioselectivities (up to 95:5 er), and branched to linear ratios (b:l) of up to 400.

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关键词

enantioselective hydroformylation,ligands,cheminform abstract,p-chiral

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