Atmospheric chemistry of (Z)-CF₃CHCHCl: products and mechanisms of the Cl atom, OH radical and O₃ reactions, and role of (E)–(Z) isomerization

Physical Chemistry Chemical Physics（2018）

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摘要

Chamber studies and G4MP2 ab initio calculations investigate isomerization in the OH radical, Cl-atom and O3 initiated oxidation of (Z)-CF3CHCHCl.

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Atmospheric chemistry of (Z)-CF3CHCHCl: products and mechanisms of the Cl atom, OH radical and O3 reactions, and role of (E)–(Z) isomerization