An unusual [4 + 2] fusion strategy to forge meso-N/O-heteroarene-fused (quinoidal) porphyrins with intense near-infrared Q-bands

Chengming Li, Lei Zhu,Wenbo Liang,Rongchuan Su,Jiangliang Yin,Yanmei Hu,Yu Lan,Di Wu,Jingsong You

Chemical Science（2019）

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摘要

Divergent synthesis of meso-N/O-heteroarene-fused (quinoidal) porphyrins was established via rhodium-catalyzed β-C–H activation/annulation of quinoidal porphyrins with alkynes.

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