Tuning effect of amorphous Fe₂O₃ on Mn₃O₄ for efficient atom-economic synthesis of imines at low temperature: improving [O] transfer cycle of Mn³⁺/Mn²⁺ in Mn₃O₄

Jiaheng Qin,Yu Long,Galian Gou,Wei Wu,Yutong Luo,Xiao Cao,Shicheng Luo,Kaizhi Wang,Jiantai Ma

Catalysis Science & Technology（2020）

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摘要

A novel Fe2O3 modified Mn3O4 catalyst (Fe5Mn5-100) has been prepared by adopting a simple co-precipitation method following low temperature baking. Fe5Mn5-100 showed exceptionally high catalytic activity for the production of imine.

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Tuning effect of amorphous Fe2O3 on Mn3O4 for efficient atom-economic synthesis of imines at low temperature: improving [O] transfer cycle of Mn3+/Mn2+ in Mn3O4

Tuning effect of amorphous Fe₂O₃ on Mn₃O₄ for efficient atom-economic synthesis of imines at low temperature: improving [O] transfer cycle of Mn³⁺/Mn²⁺ in Mn₃O₄