Photocatalytic Umpolung of N- and O-substituted alkenes for the synthesis of 1,2-amino alcohols and diols

Stephanie G. E. Amos,Stefano Nicolai,Jerome Waser

Chemical Science（2020）

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摘要

Photocatalytic Umpolung with organic dyes overcoming the innate nucleophilicity of enecarbamates and enol ethers for oxyalkynylation with EBX reagents to access 1-alkynyl-1,2-amino alcohols and diols.

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