Direct evidence for a radiation-induced synthesis of acetonitrile and isoacetonitrile from a 1 : 1 CH₄⋯HCN complex at cryogenic temperatures: is it a missing link between inorganic and prebiotic astrochemistry?

Physical Chemistry Chemical Physics（2021）

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摘要

An isolated CH4⋯HCN complex was prepared in low-temperature matrices and converted to CH3CN and CH3NC by X-ray irradiation at 6 K.

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关键词

prebiotic astrochemistry,cryogenic temperatures,synthesis,radiation-induced

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Direct evidence for a radiation-induced synthesis of acetonitrile and isoacetonitrile from a 1 : 1 CH4⋯HCN complex at cryogenic temperatures: is it a missing link between inorganic and prebiotic astrochemistry?