Pacing of late Pliensbachian and early Toarcian carbon cycle perturbations and environmental change in the westernmost Tethys (La Cerradura Section, Subbetic zone of the Betic Cordillera, Spain)

Detailed assessment of high-resolution elemental and isotopic geochemical datasets collected from the marl-limestone alternations cropping out at La Cerradura (Subbetic domain of the Betic Cordillera, Spain) and chrono- and chemostratigraphic correlation with the reference Mochras borehole (Cardigan Bay Basin, UK) unveiled valuable new insights into understanding of late Pliensbachian-early Toarcian palaeoenvironmental dynamics in a key geographical area between the northern European seaway and the Tethys Ocean. This study shows that deposition in the study area took place under dominantly oxic water column conditions, indicated, for example, by the generalized lack of enrichment in organic matter and redox metals typically associated with anoxia and euxinia. Carbon isotope stratigraphy (delta C-13(TOC)) allowed recognition of the spinatum (=emaciatum in the Submediterranean Province), Pliensbachian-Toarcian, and early Toarcian Oceanic Anoxic Event negative carbon isotopic excursions and the late Pliensbachian positive carbon isotopic excursion. It is here suggested that the observed periodic changes in lithology and sedimentary geochemistry occur at orbital frequencies (i.e. long and short eccentricity and, tentatively, precession), hinting at an astronomical control of the local-regional climate and environment during the Pliensbachian and Toarcian in the mid- to low-latitude South Iberian palaeomargin area.