(2R,4S,5S)-5-Hydroxy-4-methyl-3-oxohept-6-en-2-yl benzoate

Valeska von Kiedrowski, Claudia God, Lena Knauer,Carsten Strohmann,Hans Preut,Martin Hiersemann

IUCrData（2017）

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摘要

The title compound, C15H18O4, which crystallizes with two molecules in the asymmetric unit, was obtained in the course of the total synthesis of curvicollides A–C and fusaequisin A. It features the relative configuration of the Western aldol part of the natural products. In the crystal, molecules are linked by C—H...O hydrogen bonds.

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关键词

crystal structure,total synthesis,curvicollides A-C,Fusaequisin A,asymmetric aldol reaction,Paterson aldol reaction

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