A BF₃-mediated C–H/C–Li coupling of 1,3,7-triazapyrene with 2-thienyllithium in the design of push–pull fluorophores and chemosensors for nitroaromatics

Igor A. Lavrinchenko,Timofey D. Moseev,Mikhail V. Varaksin,Grigoriy V. Zyryanov,Olga S. Taniya,Anton N. Tsmokalyuk,Oleg P. Demidov,Ivan V. Borovlev,Valery N. Charushin,Oleg N. Chupakhin

New Journal of Chemistry（2022）

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摘要

A BF3-mediated strategy of oxidative nucleophilic substitution of hydrogen affords mono- and bis-substituted thiophene-derived 1,3,7-triazapyrene fluorophores of interest in the design of luminescent materials and chemosensors for nitroaromatics.

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A BF3-mediated C–H/C–Li coupling of 1,3,7-triazapyrene with 2-thienyllithium in the design of push–pull fluorophores and chemosensors for nitroaromatics

A BF₃-mediated C–H/C–Li coupling of 1,3,7-triazapyrene with 2-thienyllithium in the design of push–pull fluorophores and chemosensors for nitroaromatics