BF₃·OEt₂ catalyzed decarbonylative arylation/C–H functionalization of diazoamides with arylaldehydes: synthesis of substituted 3-aryloxindoles

Organic & Biomolecular Chemistry（2022）

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摘要

A metal-free BF3·OEt2 catalyzed direct decarbonylative arylation of diazoamides with readily accessible aryl aldehydes under an open-air atmosphere was developed to afford 3-aryloxindoles via 1,2-aryl migration with high selectivity.

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BF3·OEt2 catalyzed decarbonylative arylation/C–H functionalization of diazoamides with arylaldehydes: synthesis of substituted 3-aryloxindoles

BF₃·OEt₂ catalyzed decarbonylative arylation/C–H functionalization of diazoamides with arylaldehydes: synthesis of substituted 3-aryloxindoles