Unveiling anomalous lattice shrinkage induced by Pi-backbonding in Prussian blue analogues
Journal of Energy Chemistry（2022）
摘要
The pi-backbonding in Prussian blue analogues play an important role in their volume change during battery operations. The findings in this study can be applied to various organometallic compound electrodes.
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关键词
Prussian blue analogues,X-ray diffraction,X-ray absorption fine structure,Pi-backdonation,Cyanides
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