In situ science on Phobos with the Raman spectrometer for MMX (RAX): preliminary design and feasibility of Raman measurements

Yuichiro Cho,Ute Böttger,Fernando Rull,Heinz-Wilhelm Hübers,Tomàs Belenguer,Anko Börner, Maximilian Buder, Yuri Bunduki,Enrico Dietz,Till Hagelschuer,Shingo Kameda, Emanuel Kopp, Matthias Lieder,Guillermo Lopez-Reyes,Andoni Gaizka Moral Inza,Shoki Mori,Jo Akino Ogura, Carsten Paproth, Carlos Perez Canora,Martin Pertenais, Gisbert Peter,Olga Prieto-Ballesteros, Steve Rockstein, Selene Rodd-Routley,Pablo Rodriguez Perez,Conor Ryan, Pilar Santamaria, Thomas Säuberlich, Friedrich Schrandt,Susanne Schröder,Claudia Stangarone,Stephan Ulamec,Tomohiro Usui,Iris Weber, Karsten Westerdorff,Koki Yumoto

Earth, Planets and Space(2021)

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摘要
Mineralogy is the key to understanding the origin of Phobos and its position in the evolution of the Solar System. In situ Raman spectroscopy on Phobos is an important tool to achieve the scientific objectives of the Martian Moons eXploration (MMX) mission, and maximize the scientific merit of the sample return by characterizing the mineral composition and heterogeneity of the surface of Phobos. Conducting in situ Raman spectroscopy in the harsh environment of Phobos requires a very sensitive, compact, lightweight, and robust instrument that can be carried by the compact MMX rover. In this context, the Raman spectrometer for MMX (i.e., RAX) is currently under development via international collaboration between teams from Japan, Germany, and Spain. To demonstrate the capability of a compact Raman system such as RAX, we built an instrument that reproduces the optical performance of the flight model using commercial off-the-shelf parts. Using this performance model, we measured mineral samples relevant to Phobos and Mars, such as anhydrous silicates, carbonates, and hydrous minerals. Our measurements indicate that such minerals can be accurately identified using a RAX-like Raman spectrometer. We demonstrated a spectral resolution of approximately 10 cm −1 , high enough to resolve the strongest olivine Raman bands at ~ 820 and ~ 850 cm −1 , with highly sensitive Raman peak measurements (e.g., signal-to-noise ratios up to 100). These results strongly suggest that the RAX instrument will be capable of determining the minerals expected on the surface of Phobos, adding valuable information to address the question of the moon’s origin, heterogeneity, and circum-Mars material transport. Graphical Abstract
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关键词
Raman spectroscopy, Raman spectrometer for MMX (RAX), Phobos, Mineralogy, In situ analysis, Sample return, Martian Moons eXploration (MMX)
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