New insights into the selective and systematic preparation of arylgermanium hydrides

Ana Torvisco,Melanie Wolf,Michael Traxler,Dietrich Gudat,Frank Uhlig

Mendeleev Communications（2022）

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摘要

A series of novel arylgermanium hydrides ArnGeH4–n (n = 1–3) and diaryl(chloro)germanium hydrides Ar2Ge(Cl)H were synthesized and characterized. Systematic preparation and purification were achieved via the lithium chloride–triflic acid and the optimized Grignard route. Arylgermanium hydrides ArnGeH4–n (Ar = 2,5-Me2C6H3, n = 1–3) were characterized by 1H and 73Ge NMR spectroscopy and single crystal X-ray diffractometry.

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关键词

organogermanium compounds,arylgermanium hydrides,aryl(chloro)germanium hydrides,solid-state structures,1H NMR spectroscopy,73Ge NMR spectroscopy

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