Concise Synthesis of Α-Cyano Tetrahydroisoquinolines with a Quaternary Center Via Strecker Reaction

Yue Ji,Xue Zhang,Weiwei Han,Sichang Wang,Ya Wu,Keliang Zhang,Penghui Yang, Pei Xiao, Yitao Wei

RSC advances（2021）

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摘要

Concise synthesis of α-cyano tetrahydroisoquinolines with a quaternary center was successfully realized, furnishing products with up to 99% yield and an isomerization was observed under alkaline conditions, giving the isomer via [1,3]-H shift.

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