Unconformity-controlled bleaching of Jurassic-Triassic sandstones in the Ordos Basin, China

Bleaching of red beds, a type of hydrocarbon-induced alteration, is generally attributed to redox reactions between ferric iron minerals and hydrocarbon-bearing solutions. Herein, we report sandstone bleaching occurs interbedded with the coal- and dark mudstone-bearing strata at shallow depths below two unconformity surfaces separating sandstone formations of Triassic-Jurassic age in the Ordos Basin, China. Field observations, petrography, and geochemistry suggest that uplift events controlled the formation of red beds via supergene alteration and bleaching via hydrocarbon circulation. The color of sandstones below the unconformities grade from red, yellow, and white colors at shallow depths (few meters to tens of meters) to dark yellow, gray-green and gray colors at deeper depths. Organic matter (carbonaceous plant debris) and pyrite in the unaltered sandstone gave rise to the gray color. The red/yellow sandstones are characterized by the presence of extensive iron oxide/ hydroxide grain coatings, exhibit intense dissolution and extensive kaolinization of detrital feldspar and biotite and lithics and are mainly composed of detrital quartz. The white, bleached sandstone presents similar petrographic characteristics as the unbleached sandstone except for a lack of iron oxide/hydroxide cements. 818OVSMOW (9.8%, to 15.8%,) and 8DVSMOW (- 103%, to -119%,) values of kaolinite, and chemical indices of alteration of sandstones indicate a weathering origin for the kaolinite and the dissolution of labile minerals in the red and yellow sandstones. The original color of the bleached sandstone was gray during very early diagenesis and shifted to red/yellow due to the oxidation of pyrite and ferromagnesian silicate minerals (e.g., biotite) into hematite or goethite cements by the meteoric water circulation during regional uplift following the deposition of each formation. Supergene alteration associated with unconformities also created significant secondary porosity, and allowed later hydrocarbons to flow along the unconformities. The lithological properties of the weathered rocks below unconformities are highly heterogeneous both vertically and laterally and have a significant influence on fluid flow. This study provides direct evidence for hydrocarbon migration along unconformities and improves understanding of fluid-rock interaction in subsurface reservoirs.