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Chemical and Physical Effects of Polyurethane-Precursor-based Reactive Modifier on the Low-Temperature Performance of Bitumen

Construction and Building Materials(2022)

Harbin Inst Technol | BASF Polyurethane Specialties China Co Ltd | Intelligent Transport System Research Center | Jilin Traff Planning & Design Inst | Hong Kong Polytech Univ | Rhein Westfal TH Aachen

Cited 22|Views40
Abstract
The use of novel polyurethane-precursor-based reactive modifier (PRM) to produce high-performance modified bitumen provides great benefits in terms of both performance improvement and environmental protection. Given the complexity of the chemical composition of bitumen, its chemical interaction with PRM and the modification effect on bitumen performance are of great interest. To fundamentally understand the chemical reactions and low-temperature behaviours of PRM-modified bitumen, physicochemical characterisations and quantum chemical calculations were performed from chemical, thermal, morphological, and mechanical aspects. The results were interpreted based on the reactions between PRM and bitumen model compounds. It shows that the carbamate, urea, and amide linkages are formed by the reactions of PRM with active sites in asphaltenes and resins, which eventually cause crosslinking polymerisation owing to the asphaltene fraction. The modification process promotes the conversion of the resin to asphaltene and reconfiguration of asphaltene, which accordingly increases the facilitation of the natural segregation of maltene and asphaltene. With the strengthening of the reconfiguration and crosslinking of asphaltene molecules, considerably improved stiffness and fracture resistance are observed. However, the concurrent changes in bitumen composition and chemical structures result in a slight increase followed by a decrease in the low-temperature properties with an increase in the PRM concentration. In the presence of excessive PRM, the modified bitumen becomes more susceptible to large deformations. This study not only provides a reference for understanding the PRM modification mechanism but could also serve as a guidance for the further application of PRM-modified bitumen.
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Key words
Modified bitumen,Polyurethane-precursor-based Reactive,Modifier (PRM),Low-temperature performance,Physicochemical properties,Mechanism investigation
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要点】:研究了一种新型聚脲预聚物基反应改性剂(PRM)对沥青低温性能的改善及其化学和物理效应,揭示了改性机制并提供了改性沥青应用指导。

方法】:通过物理化学表征和量子化学计算,从化学、热学、形态学和力学角度研究了PRM与沥青的化学反应及低温行为。

实验】:使用PRM与沥青模型化合物进行反应,发现形成了碳酰胺、脲和酰胺键,导致沥青质分子交联聚合,从而提高了刚度和断裂阻力;实验使用的数据集名称未提及,但结果表现为低温度性能随PRM浓度增加先略微上升后下降。