Conversion of a double‐tetranuclear cluster silver helicate into a dihelicate via a rare desulfurization process

Sandra Fernández-Fariña,Luis Miguel González-Barcia,María José Romero,Javier García-Tojal,Marcelino Maneiro,José Manuel Seco,Guillermo Zaragoza,Miguel Martinez-Calvo,Ana M. González-Noya,Rosa Pedrido Castiñeiras

Inorganic Chemistry Frontiers（2022）

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摘要

We present the first example of a silver double‐tetranuclear cluster helicate [Ag4L2]2 obtained from a bisthiosemicarbazone ligand using electrochemical synthesis. This cluster helicate undergoes a rare desulfurization process in chloroform...

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