The Underlying Molecular Mechanism of Fence Engineering to Break the Activity‐stability Trade‐off of Catalysts

Angewandte Chemie(2021)

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摘要
Non-precious-metal (NPM) catalysts often face the formidable challenge of a trade-off between long-term stability and high activity, which has not yet been widely addressed. Here we propose distinct molecule-selective fence as a promising novel concept to solve this activity-stability trade-off. This unique fence has the characteristics of preventing poisonous species from invading catalysts, but allowing catalytic reaction-related species to diffuse freely. We applied this concept to construct CoS2 layer with the function of molecular selectivity on the external surface of highly active Co doped MoS2, achieving a remarkable catalytic stability towards alkaline hydrogen evolution reaction, along with a further optimized activity. In situ spectroscopy technologies uncovered the underlying molecule mechanism of the CoS2 fence for breaking the activity-stability trade-off of the MoS2 catalyst. This work offers valuable guidance for rationally designing efficient and stable NPM catalysts.
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