Rear side dielectrics on interdigitating p(+)-(i)-n(+) back-contact solar cells - hydrogenation vs. charge effects

EPJ PHOTOVOLTAICS(2021)

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摘要
Polysilicon-on-oxide (POLO) passivating contacts and interdigitated back-contact (IBC) cell technologies have recently attracted a lot of interest as candidates for the implementation in the next generation of solar cells. An IBC cell with POLO junctions for both polarities - a POLO2-IBC cell - has to electrically isolate the highly defective p(+) and n(+) poly-Si regions on the rear side of the cell to avoid parasitic recombination. Inserting an initially undoped, intrinsic (i) region between the p(+) and n(+) poly-Si regions was demonstrated to successfully prevent the parasitic recombination in the transition region of ISFH's 26.1%-efficient POLO2-IBC cell. In order to further improve the conversion efficiency towards 27%, we apply hydrogen-donating dielectric layer stacks to the p(+)-(i)-n(+) POLO interdigitating rear side to enhance the passivation quality of the POLO junctions. We indeed show a significant improvement of POLO junctions on symmetrical full-area homogenously doped reference samples, but when we apply a hydrogen-donating layer stack on the p(+)-(i)-n(+) POLO interdigitating rear side, we observe a strong degradation in the performance of the POLO2-IBC cell. We attribute this to the formation of a conductive channel between the p(+) and n(+) poly-Si regions due to the strong negative charge density of the hydrogen-donating layer stack.
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关键词
POLO, IBC, hydrogenation, charge, recombination, passivating contact, polysilicon
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