Structural speciation in chemical reactivity profiling of binary-ternary systems of Ni(II) with iminodialcohol and aromatic chelators
Polyhedron(2022)
摘要
Systematic synthetic reactivity in binary-ternary Ni(II):iminodipropanol:N,N’-aromatic chelator systems unravels an interwoven network of hybrid mononuclear Ni(II) complexes with variable coordination sphere composition. Structural variant and interconversion transformations exemplify distinct physicochemical properties, revealing diverse lattice architecture-spectroscopic correlations with theoretical electronic modeling and formulating nickel chemical reactivity profiles-patterns useful in materials development.
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关键词
Nickel complex synthesis,Iminodialcohol ligand,Structure elucidation,Magnetic properties,Chemical reactivity patterns
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