Evolution of Archean Sanukitoids from the Otto Stock by Magma Mixing and Na-K Metasomatism: Evidence from Petrological Observations and Lithium Isotope Geochemistry

Petrogenetic models for the genesis of Archean sanukitoids are diverse in the literature but most point to the initiation of plate tectonics and the construction of the first proto-continents during the Late Archean. These rocks include diorites, monzonites, monzodiorites, quartz monzodiorites, trachyandesites, granodiorites and tonalites, and are defined as having SiO2 = 55-60 wt%, Na2O + K2O = 6 wt%, MgO > 6 wt%, Mg# > 60, Ni-Cr > 100 ppm, Sr and Ba = 600-1800 ppm, chondrite-normalized Ce and Yb values of 80-250 and 4-10, respectively, and no Eu anomalies. Petrogenetic models include the partial melting of mantle peridotite previously metasomatized by fluids of crustal or mantle origin, partial melting of subducted slabs and assimilation of peridotite, and partial melting of undepleted peridotite with subsequent mixing with tonalite-trondhjemite-granodiorite (TTG) crustal partial melts and addition of carbonatite, all of which may or may not include subsequent differentiation by fractional crystallization. Here, extraordinary textural relations unequivocally show that at the Late Archean Otto stock, Abitibi, Canada, sanukitoids resulted from the assimilation of clinopyroxenite by monzonitic magmas and coeval magmatic-hydrothermal Na-K metasomatism. The metasomatized monzonites (+/- quartz), melanogranites, granodiorites, and sanukitoidal melanoporphyries were subsequently cut by swarms of lamprophyre dykes hosting a different set of hydrothermal alteration assemblages, including propylitic alteration, biotitization, chloritization, and pyritization, along with associated enrichments in Au. These alterations are shown to be associated with the nearby Cadillac-Larder Lake Fault Zone and the world-class Kirkland Lake gold deposit. The Li isotopic compositions of these rocks correlate with Au concentrations and range from magmatic values of similar to +4 parts per thousand up to +10.4 parts per thousand in Na-K metasomatized and Au-depleted rocks, and from magmatic values of similar to 4 parts per thousand down to 0.6 parts per thousand in rocks hosting propylitic, chloritic, and biotitic alteration and Au enrichments of up to 2.9 ppm Au.