From Imines to Amides Via NHC-mediated Oxidation

Shaofa Sun,Donghui Guo,Fangyi Li,Jian Wang

Organic chemistry frontiers（2022）

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摘要

The unprecedented NHC-mediated oxidation of imines to amides is described. This protocol features broad substrate scope and allows rapid assembly of amides in good to high yields. Notably, this process includes not only the umpolung of imines, but also the discovery of NHC-bound 1,2-dioxetane intermediates.

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