Iron Carbon Catalyst Initiated the Generation of Active Free Radicals without Oxidants for Decontamination of Methylene Blue from Waters

In conventional oxidation technologies for treatment of contaminated waters, secondary pollution of the aqueous environment often occurs because of the additional oxidants generated during the process. To avoid this problem, Fe/NG catalyst composites without additives were developed in this study for decontamination of methylene blue (MB) from waters. The Fe/NG catalyst, composed of carbon nitride and iron chloride (FeCl3 center dot 6H(2)O), was prepared by high temperature pyrolysis. It is an exceptionally efficient, recoverable, and sustainable catalyst for degradation of organic matter. The morphological characteristics, chemical structure, and surface properties of the catalyst composites were investigated. The catalyst exhibited high MB removal efficiency (100%) within 30 min under ambient temperature and dark conditions. The experiments indicated that an MB degradation effect was also applicable under most acid-base conditions (pH = 2-10). The characterization results using electron spin resonance and analysis of intermediate products demonstrated that free radicals such as center dot OH and center dot O-2(-) were produced from the Fe/NG composites in the heterogeneous system, which resulted in the high MB degradation efficiency. Moreover, the catalysis reaction generated reducing substances, triggering iron carbon micro-electrolysis to spontaneously develop a microcurrent, which assisted the degradation of MB. This study demonstrates the feasibility of Fe/NG catalysts that spontaneously generate active species for degrading pollutants in an aqueous environment at normal temperature, providing an attractive approach for treating organic-contaminated waters.