Effect of the Precursor Aggregate State on the Synthesis of CNTs in a DC Plasma Jet

The transformation of various carbonaceous substances into ordered carbon nanostructures is a fundamental process in nanotechnology. Since this structural transformation is a common property of various methods for producing CNTs, understanding the mechanism of this process in the bulk of a plasma jet will be extremely important, since no substrates are used here. We present an experimental and numerical study of the synthesis of CNTs with and without external catalysts for the pyrolysis of soot, acetylene, and ethanol in a DC argon plasma at a pressure of 350 Torr. By combining various physical methods, including simultaneous thermal analysis, diffraction analysis, electron microscopy, and energy dispersive analysis, we will show that the aggregation state of the precursor significantly affects the structural and morphological properties of CNTs. Theoretical calcula-tions under the assumption of local thermodynamic equilibrium made it possible to study the gas phase composition of a plasma flow in which the CNT precursor is nucleated. It was found that during the pyrolysis of soot (C), the condensation temperature of solid carbon is 3672 K, with the hydrogen in precursor (C2H2) it is lower and equals 3353 K, with the addition of oxygen (C2H5OH) its value becomes even < 3141 K. At the lowest condensation temperature, the most thermally stable CNTs are formed.