Mechanosynthesis of multiferroic hybrid organic-inorganic [NH4][M(HCOO)3] M = Co2+,Mn2+,Zn2+,Ni2+, Cu2+ formate-based frameworks

Journal of Alloys and Compounds(2022)

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摘要
•Mechanosynthesis as new route to synthesize [NH4][M(HCOO)3] compounds•Dehydration process of metal formate as first step of the synthesis•XRD and Raman spectroscopy indicate single phase product for all the compositions explored
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关键词
Mechanosynthesis,Hybrid organic-inorganic materials,Metal-organic frameworks
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