Silica gels grafting with upper rim tetraphosphorylated tetrahydroxy(thia)calixarenes. Europium(III) sorption
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS(2022)
摘要
Sequential treatment of silica gel with tetrachlorosilane and cone-shaped tetraphosphorylated tetrahydroxy(thia)calixarenes yielded porous organo-inorganic sorbents, the surface of which is covered by spatially ordered phosphonate, phosphinate and phosphine oxide groups capable of co-operative binding of metal cations. Sorption of europium(III) by the modified silica gels was studied.
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关键词
Calixarenes,organophosphorus ligands,silica gel,sorbents,europium
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