Rapid oxidation of 4-cholorphenol in the iron-based Metal–Organic frameworks (MOFs)/H2O2 system: The ignored two-steps interfacial single-electron transfer

Yi Han,Mingjie Huang,Wei Xiang,Chen Wang,Yongjie Li,Xiaohui Wu,Juan Mao,Tao Zhou, Hong Li, Deming Wu

Separation and Purification Technology（2022）

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摘要

•Two-steps single-electron transfer from H2O2 to 4-CP occurred in initial lag phase.•O2•–-generated intermediate HQ was critical to start the following rapid decay phase.•Pheonlic organics were selectively degraded by forming reductive benzenediols.•Mechanism was proposed with an effective heterogeneous-homogeneous iron cycle.

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关键词

Metal-organic frameworks (MOFs),Single-electron transfer,4-chlorophenol,Heterogeneous Fenton like oxidation,Benzenediols intermediates

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