Solubility of REM Oxides in Chloride–Fluoride and Fluoride Melts

A. B. Ivanov,V. A. Volkovich, A. V. Shchetinskii, A. S. Mukhamadeev,A. A. Ryzhov,A. I. Petrov

Russian Metallurgy (Metally)（2022）

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摘要

The solubilities of oxides of rare-earth elements (yttrium, lanthanum cerium, praseodymium, neodymium, samarium) in molten mixtures of calcium and barium chlorides and fluorides, namely, CaCl 2 –CaF 2 (20 and 75 mol % CaF 2 ), BaCl 2 –BaF 2 (15 and 73 mol % BaF 2 ), and CaF 2 –BaF 2 (50 mol % BaF 2 ), at temperatures up to 1400°C are studied by an isothermal saturation method.

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关键词

yttrium, lanthanum, cerium, praseodymium, neodymium, samarium, oxide, solubility, chloride–fluoride melts

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