Testing the equilibrium model: An example from the Caledonian Kalak Nappe Complex (Finnmark, Arctic Norway)

The equilibrium model has been tested using Barrovian garnet-zone micaschists of the Kalak Nappe Complex. In our model, equilibrium in the MnNCKFMASHT system was established across the entire rock volume during prograde metamorphism except for garnet, which developed growth zoning preserved at levels controlled by the kinetics of intracrystalline diffusion. The preservation potential of the disequilibrium fluctuations required for nucleation of garnet has been considered in our simulations, using a moving boundary multicomponent diffusion and growth model. Results indicate that the core of garnet that crystallizes during regional metamorphism does not retain the major element composition of the nucleus but reflects the compositional signature of the immediate overgrowth. The differences between the metamorphic conditions of successive garnet growth steps of the samples indicate characteristic trends in their pressure-temperature evolutions that can be predicted with the equilibrium model. There is some latitude with regard to the absolute metamorphic conditions due to the inherent uncertainty of the thermodynamic data and the approximation of the reactive volume composition. However, the slopes of the pressure-temperature paths together with systematic trends in the lithological, geochemical, and Lu-Hf garnet whole-rock isotopic properties of the rocks, as well as their garnet crystal size frequency distributions, enable the identification of the Veidnes, Bekkarfjord, and Kolvik Nappes involved in the Caledonian Orogeny and provide new insight into their metamorphic evolutions. According to our findings, the base of the Kalak Nappe Complex experienced wide-spread Barrovian-type metamorphism at c. 420 Ma with a gradient of similar to 40 bar/degrees C and peak conditions of similar to 560 degrees C and 6.7 kbar in the Bekkarfjord and Veidnes Nappes, whereas the hinterland-placed Kolvik Nappe was metamorphosed at peak conditions of similar to 590 degrees C and 7.5 kbar. This event was preceded by moderate-pressure metamorphism at c. 423 Ma resulting in garnet crystallization exclusively in the Bekkarfjord Nappe, along a gradient of similar to 20 bar/degrees C and peak conditions of similar to 570 degrees C and 6.0 kbar. We consider both of these metamorphic and deformational episodes to be different stages of the Scandian phase during the Caledonian Orogeny. An additional orogenic event at c. 464 Ma is preserved in the Veidnes Nappe, which was juxtaposed with the Scandian Nappes by repeated out-of-sequence thrusting associated with the final continent-continent collision. This nappe provides a unique insight into an earlier stage of the Caledonian Orogeny, indicating a low-pressure Barrovian-type metamorphic history with a gradient of similar to 15 bar/degrees C and peak conditions of similar to 560 degrees C and 4.5 kbar.