Metallofullerene single-molecule magnet Dy2O@C2v(5)-C80 with a strong antiferromagnetic Dy⋯Dy coupling

Georgios Velkos,Wei Yang,Yang-Rong Yao,Svetlana M Sudarkova,Fupin Liu,Stanislav M Avdoshenko,Ning Chen,Alexey A Popov

Chemical Communications（2022）

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摘要

Dysprosium-oxide clusterfullerene Dy2O@C2v(5)-C80 is a single-molecule magnet featuring antiferromagnetic superexchange Dy⋯Dy coupling via the μ2-O2− bridge, the strongest of its kind among {Dy2} complexes with non-radical bridges.

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