Conductive Co-triazole metal-organic framework exploited as an oxygen evolution electrocatalyst
Chemical Communications(2022)
摘要
A Co-triazole metal-organic framework (Co-trz) endowed with electrical conductivity was synthesized effortlessly via a microwave-based method. Providing a high density of catalytic centers with electrically conductive features, as suggested by DFT calculations, the framework exhibited a low overpotential for the oxygen evolution reaction (OER) with good kinetics. A mechanistic reaction pathway was proposed based on monitoring alterations in the oxidation state and local coordination environment of Co centers upon the occurrence of the OER. Due to its performance and its chemical and electrochemical robustness, the framework was highlighted as a promising MOF electrocatalyst for the OER.
更多查看译文
关键词
Metal-Organic Frameworks,Electrolyte Design
AI 理解论文
溯源树
样例
生成溯源树,研究论文发展脉络
Chat Paper
正在生成论文摘要