Effect of silane coupling agents on flowability and compressibility of compound for bonded NdFeB magnet

Journal of Rare Earths(2022)

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摘要
Based on the difference of the Y-terminal functional group of the silane coupling agent (Y–Si(X)3), four different silane coupling agents were employed to pretreat the surface of the NdFeB powders. The effects of silane coupling agents on the flowability and compressibility of compounds for preparing bonded NdFeB magnets were studied. It is indicated that compounds pretreated by silane coupling agents have weaker friction and meshing force. The apparent density is increased by 0.3 g/cm3 compared with the compound without silane coupling agent, and the radial crushing strength is significantly increased by about 3–4 times. In addition, the epoxy resin is more evenly distributed on the surface of the compounds treated by silane coupling agents observed by scanning electron microscopy, and some agglomerated particles are produced. Also, the compressibility of compounds with silane coupling agents is significantly improved due to the fact that hardening exponents are reduced. However, the addition of silane coupling agents has almost no effect on the magnetic properties of bonded magnets. The special energy was used to manifest the flowability of magnetic powder particles representing the macroscopic performance of the force between powder particles, providing a new direction for the study of the interface compatibility of two-phase or multiphase composite materials.
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关键词
Bonded NdFeB magnets,Silane coupling agent,Flowability,Special energy,Compressibility,Rare earths
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