Cationic Organometallic Complexes of Group 12 Metals: A Decade of Progress Toward the Quest of Novel Lewis Acidic Catalysts

Samuel Dagorne,Pierre de Frémont, Nicolas Adet,Jordan Parmentier, Xuejuan Xu,Béatrice Jacques

SSRN Electronic Journal（2022）

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摘要

•Group 12 metal organocations are comprehensively reviewed since 2010.•N-heterocyclic carbenes are currently ligands of choice for robust Zn and Hg cations.•Zn organocations may be stable, tunable and potent Lewis acidic catalysts.•Zn organocations catalyze the functionalization of various unsaturated organics.

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COD,Cp*,DMSO,DMT,DOSY NMR,[BArF20]-,[BArF24]-,CAAC,DCM,Dbf,Dipp,DMAP,equiv.,FIA,h,IB,IR,LA,Lact,MALDI-TOF,Mes,Mn,MS,Mw,NHC,NMR,NTf2-,o-dfb,PDI,PIB,Pipp,PLA,SC-XRD,THF,ROP,r.t.,tol,TOF,Vs,WCA

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