The synthesis of aminophenyl-substituted 2,2′-bipyridine ligands by “1,2,4-triazine” methodology

Alexey P. Krinochkin,Dmitry S. Kopchuk,Maria I. Savchuk,Yaroslav K. Shtaitz,Ekaterina S. Starnovskaya,Eugeny B. Gorbunov, Svetlana S. Rybakova, Ekaterina A. Kudryashova,Grigory V. Zyryanov,Oleg N. Chupakhin

MODERN SYNTHETIC METHODOLOGIES FOR CREATING DRUGS AND FUNCTIONAL MATERIALS (MOSM2020): PROCEEDINGS OF THE IV INTERNATIONAL CONFERENCEAIP Conference Proceedings（2021）

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摘要

A convenient synthetic approach to the 2,2’-bipyridines, including those with a condensed cyclopentene fragment, having an aminophenyl substituent at the C5 or C6 positions is reported. The products were obtained via their 1,2,4-triazine analogs with a nitro group, by the subsequent transformation of their 1,2,4-triazine ring into a pyridine one and the reduction of the nitro group to the amino group.

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关键词

ligands,synthesis,aminophenyl-substituted

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