Cu(II)/SPDO complex-catalyzed asymmetric Baeyer–Villiger oxidation of 2-arylcyclobutanones and its application for the total synthesis of eupomatilones 5 and 6

Chang-Sheng Zhang,Ya-Ping Shao,Fu-Min Zhang,Xue Han,Xiao-Ming Zhang,Kun Zhang,Yong Qiang Tu

Chemical Science（2022）

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摘要

A novel classical kinetic resolution of 2-aryl substituted or 2,3-disubstituted cyclobutanones of Baeyer–Villiger oxidation catalyzed by a Cu(II)/SPDO complex is reported for the first time, producing normal lactones in excellent...

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关键词

complex catalyzed asymmetric baeyer–villiger,baeyer–villiger oxidation,synthesis,eupomatilones

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