Palladium‐Catalyzed Reaction of 2,3‐Allenols with Amines: Synthesis of [3]Dendralenes and 1,3‐Dienes Containing Allylic Amino and Hydroxy Groups

Advanced Synthesis & Catalysis（2022）

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摘要

Palladium-catalyzed reaction of 2,3-allenols with amines was carried out to construct conjugated polyenes with allylic amino and hydroxy groups. [Pd(pi-allyl)Cl](2)/P(2-furyl)(3)-catalyzed reaction in MeOH led to (Z)-configurated [3]dendralene derivatives and Pd(OAc)(2)/P(2-furyl)(3)-catalyzed reaction in iPrOH resulted in (1Z,3E)-1,3-diene derivatives.

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关键词

allylaminoalcohol, [3]dendralene, 1,3-diene, 2,3-allenol, palladium catalysis

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