Structural diversity in the series of lanthanide complexes [Ln(Ph3PO)n(NCS)3] (n = 3, 4)

Lawrence Chan,Simon A. Cotton, Joanna Dickson (nee Harris),Andrew W. G. Platt,Paul R. Raithby,Stefanie Schiffers, Alexander Tait,John E. Warren

Polyhedron（2022）

引用 1|浏览9

暂无评分

摘要

Two unique series of lanthanide complexes [Ln(Ph3PO)n(NCS)3] (n = 3, 4) have been structurally characterised. For the metals Sm-Tb both seven and six coordinate complexes can be isolated and structurally characterised suggesting a structural equilibrium in solution.

查看译文

关键词

Lanthanides,Lanthanide contraction,Phosphine oxide,Thiocyanate,Crystal structures

AI 理解论文

溯源树

样例

生成溯源树，研究论文发展脉络

Chat Paper

正在生成论文摘要