Nd3+-Y3Al5O12 system: Iso-valent substitution driven structural phase evolution and thermo-physical behavior

Koushik Bhandari,V Grover,Anushree Roy,Manjulata Sahu,R. Shukla,Joydipta Banerjee

Journal of Molecular Structure（2022）

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摘要

•Y3-xNdxAl5O12 system studied to mimic substituted garnets for MA transmutation.•Synthesis route enabled stabilization of 33 mol% Nd3+ substituted garnet observed.•Incorporation of Nd3+ causes expansion of the cubic garnet phase.•Stabilization of defect stabilized rhombohedral NdAlO3 in Nd3+-rich region.•Thermal conductivity/thermal expansion decrease with Nd3+ incorporation in Y3Al5O12.

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关键词

Yttrium aluminium garnet,XRD,Thermal conductivity,Minor actinide transmutation

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