Synthesis of 1,2-diselenides via potassium persulfate-mediated diselenation of allenamides with diselenides.
Organic & Biomolecular Chemistry(2022)
摘要
An efficient potassium persulfate-mediated radical addition of allenamides with diselenides was developed to create a workable route to 1,2-diselenide products. The reaction tolerates a wide spectrum of functional groups to deliver the products in good to excellent yields. Mechanistic investigations including a calculation study indicated that the radical cascade proceeds through a vinyl radical intermediate, which is formed a selenium radical added to the terminal CC double bond of allenamides.
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关键词
allenamides,synthesis,diselenation,potassium,persulfate-mediated
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