The simultaneous control over the alternating sequence and the inner-core position of the mesogenic segments in side-chain liquid crystal polymers

Ruixue Zhang,Hongwei Ma,Xuwen Li,Bo Wang,Chao Li, Wen Liao,Yang Li,Li Han

Journal of Molecular Liquids（2022）

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摘要

•Four mesogenic moieties with the tuned inner-core position were synthesized.•Alternating-arranged SCLCPs were prepared through combining LACOP and hydrosilylation.•The simultaneous control over the sequence and the inner-core position of the mesogenic segment was realized in the resulting SCLCPs.•Interior structure–property relation of mesogenic moieties and SCLCPs was investigated.

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关键词

Living anionic copolymerization,Side-chain liquid crystal polymers,Alternating sequence,Azobenzene (Azo),Trifluoromethyl (CF3) groups

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