Facile preparation of tremella-like TiO 2 /Cd:ZnIn 2 S 4 photoanode with enhanced photo-electro-chemical (PEC) performance for energy and environmental applications.

The realization of solar-driven photoelectrochemical (PEC) process lies in the success development of materials with excellent photoelectric properties. Past reports identified TiO, upon modified with both Cd and ZnInS (ZIS), exhibits promising PEC performance; however, at the cost of tedious preparation. In view of this, our work proposes a facile one-step hydrothermal strategy to deposit both modifiers onto the pre-obtained TiO nanotubes (NTs), realizing rose-like TiO/ZnInS (TiO/ZIS) or tremella-like TiO/Cd:ZnInS (TiO/Cd:ZIS) with improved PEC performances. Interestingly, the thickness of ZIS petals, which deposited on top of TiO NTs, is positively-correlated to its Cd-composition, signifying the substitutional doping of Cd into the unit cell of ZIS. This renders robust ionic interactions between the constituents, prompting the enhanced optical properties of TiO in conjecture to its reduced impedance. As a result, the recombination rate of photo-electric-derived carriers was drastically suppressed, with an improved photocurrent density of 606.2 μA cm recorded by TiO/Cd:ZIS photoanode under solar irradiation. Such performance is 80 times and 5.16 times higher than those of bare TiO NTs and TiO/ZIS counterparts. The photoconversion efficiencies in terms of incident photon-to-current conversion efficiency (IPCE) and applied bias photon current efficiency (ABPE) for TiO/Cd:ZIS were significantly improved too, recorded at 1.12% and 0.38%, respectively, under standard evaluation condition. As summary, our work proposes a facile one-step hydrothermal approach that simultaneously-deposit both Cd and ZIS onto TiO photoanode for an enhanced PEC performance. This opens up a wider horizon for PEC technology, further unlocking its potential in both energy and environmental applications.