Tungsten(II) chloride hydrates with high solubility in chloroaluminate ionic liquids for the electrodeposition of Al–W alloy films

Journal of Electroanalytical Chemistry(2022)

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摘要
•Tungsten(II) chloride hydrates showed high solubility in AlCl3-based ionic liquids.•Al–W alloy films with high W contents were obtained at high current densities.•Current efficiencies close to 100% were achieved even in the baths with hydrates.•Spectroscopic techniques were used to identify the chemical species in the bath.
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关键词
Ionic liquid,Water,Aluminum alloy,Electrodeposition,Spectroscopy
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