High-Efficiency Continuous-Luminescence-Controllable Performance and Antithermal Quenching in Bi 3+ -Activated Phosphors.

Recently, Bi-activated phosphors have been widely researched for phosphor-converted light-emitting diode (pc-LED) applications. Herein, novel full-spectrum ABO:Bi (A = Gd, La; B = Sb, Nb) phosphors with a luminescence-tunable performance were achieved by a chemical substitution strategy. In the LaSbO host material, a new luminescent center was introduced, with Gd replacing La. The photoluminescence (PL) spectra show a large blue shift from 520 to 445 nm, thus achieving regulation from green to blue lights. Moreover, a series of solid solution-phase phosphors LaSbNbO:Bi were prepared by replacing Sb with Nb, and a PL spectral tunability from green (520 nm) to orange-red (592 nm) was realized. Temperature-dependent PL spectra show that LaGdSbO:Bi phosphors have excellent thermal stability. Upon 350 nm excitation, the PL intensity of LaGdSbO:Bi phosphors at 150 °C remained at more than 93% at room temperature. With Gd doping, the thermal stability gradually improved, and LaGdSbO:0.03Bi represents splendid antithermal quenching (135.2% at 150 °C). Finally, a full-visible spectrum for pc-LED with a high color-rendering index (Ra = 94.4) was obtained. These results indicated that chemical substitution is an effective strategy to adjust the PL of Bi, which is of great significance in white-light illumination and accurate plant lighting.