Synthesis and DFT conformational analysis of trimethyl-functionalized [2.2]metacyclophanes and their Lewis-acid assisted reactions

Md Monarul Islam,Chuan-Zeng Wang,Bigyan Sharma,Shofiur Rahman,Paris E. Georghiou,Abdullah Alodhayb,Taisuke Matsumoto,Junji Tanaka,Takehiko Yamato

Journal of Molecular Structure（2022）

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摘要

•Strained anti-[2.2]metacyclophanes were synthesized by sulfur extraction method.•Lewis acid-catalyzed reactions of anti-[2.2]MCP led to transannular cyclization.•DFT studies were carried out to understand relative stability of different isomers.

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关键词

Metacyclophane,Syn-anti isomerization,Lewis acid catalysis,Transannular reaction,DFT

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