Improved Rotational Foam Molding Properties of Tailored Polyethylene Blends with Higher Crystallization Temperature and Viscosity-Temperature Sensitivity
POLYMERS(2022)
摘要
Rotational foam molding has attracted more and more attention due to the inexpensive machines required, low residual stresses, and flexible design for special and high-value-added applications. However, it is a great challenge to control cell sizes and morphology because of its coalesce and collapse during prolonged heating or at different temperatures. A novel tailored polyethylene blend with a unique chain structure for rotational foam molding was creatively proposed and demonstrated, and the effects of crystallization temperature and viscosity-temperature sensitivity on foaming were also investigated. The polyethylene blends with few chain branches in the low-molecular-weight part and many chain branches in the high-molecular-weight part effectively improved the crystallization temperature and the viscosity-temperature sensitivity for better prevention of coalesce and collapse during the foam-shaping stage.
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关键词
polyethylene,rotational molding,foams,crystallization,viscosity-temperature sensitivity,morphology,cell sizes
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