Synthesis of Fully Exposed Single‐Atom‐Layer Metal Clusters on 2D Ordered Mesoporous TiO2 Nanosheets

A sulfhydryl monomicelles interfacial assembly strategy is presented for the synthesis of fully exposed single-atom-layer Pt clusters on 2D mesoporous TiO2 (SAL-Pt@mTiO(2)) nanosheets. This synthesis features the introduction of the sulfhydryl group in monomicelles to finely realize the controllable co-assembly process of Pt precursors within ordered mesostructures. The resultant SAL-Pt@mTiO(2) shows uniform SAL Pt clusters (approximate to 1.2 nm) anchored in ultrathin 2D nanosheets (approximate to 7 nm) with a high surface area (139 m(2) g(-1)), a large pore size (approximate to 25 nm) and a high dispersion (approximate to 99 %). Moreover, this strategy is universal for the synthesis of other SAL metal clusters (Pd and Au) on 2D mTiO(2) with high exposure and accessibility. When used as a catalyst for hydrogenation of 4-nitrostyrene, the SAL-Pt@mTiO(2) shows a high catalytic activity (TOF up to 2424 h(-1)), 100 % selectivity for 4-aminostyrene, good stability, and anti-resistance to thiourea poisoning under relatively mild conditions (25 degrees C, 10 bar).