Two novel 4,6-connected anion-pillared metal-organic frameworks for simultaneous separation of C3 and C4 olefins

Yuan Liu,Yan Zhang,Peixin Zhang,Yong Peng,Xing Liu,Jingwen Chen,Shixia Chen,Zheling Zeng,Jun Wang,Shuguang Deng

Chemical Engineering and Processing - Process Intensification（2022）

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摘要

•Two new 4,6-connected fsc-net anion-pillared MOFs are reported.•Two distinct pores are obtained in the as-synthesized anion-pillared MOFs.•Efficient separation of both C3 and C4 olefins is achieved.•High uptake capacity and selectivity for C3H6 and C4H6 are obtained.

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关键词

Metal-organic frameworks,Adsorptive separation,Propylene,1,3-butadiene

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