PIFA-promoted intramolecular oxidative cyclization of pyrrolo- and indolo[1,2-a]quinoxalino-appended porphyrins: an efficient synthesis of meso,beta-pyrrolo- and indolo[1,2-a]quinoxalino-fused porphyrins
ORGANIC & BIOMOLECULAR CHEMISTRY(2022)
摘要
We have developed an efficient protocol for the synthesis of meso,beta-pyrrolo- and indolo[1,2-a]quinoxalino-fused porphyrin systems 7-9 by PIFA-promoted intramolecular oxidative cyclization of easily accessible meso-pyrrolo- and indolo[1,2-a]quinoxalino-appended porphyrins 6a-j. The absorption spectra of meso,beta-pyrrolo- and indolo[1,2-a]quinoxalino-fused porphyrins 7-9 displayed bathochromic shifted (100-150 nm) and broadened Soret bands and Q bands in addition to intense band near IR region. The indolo[1,2-a]quinoxalino-fused porphyrin 9bZn with lower fluorescence quantum yield (0.003) and reduced energy gap (similar to 1.3 eV) was found to sensitize singlet oxygen effectively.
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