Synthesis and structural characterization of nitro-functionalized cyclic hypervalent iodine compounds

Guobi Li,Arnold L. Rheingold,John D. Protasiewicz

Polyhedron（2022）

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摘要

The results of four structural determinations on three different cyclic iodonium compounds having an NO2 substituent reveal I⋯O intermolecular interactions with counterions (OTf−) or solvent molecules (THF, DMF, or DMSO).

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关键词

Cyclic iodonium compounds,Secondary bonding,Halogen bonding,Crystal structures,Hypervalent iodine compounds

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